Angewandte Chemie (International ed. in English)
Asymmetric Hydride Shift Reactions Catalyzed by Chiral Aluminium Complexes.
Mostafa M Amer, Jingyan Hou, Jinfang Wang, Akvile Mazeikaite, Timothy J Donohoe
Published: 202610.1002/anie.202521374
Abstract
An asymmetric intramolecular hydride shift reaction has been developed that is catalyzed by Al Lewis acids in conjunction with a chiral BINOL-derived ligand. Racemic THP substrates are transformed into cyclohexene products via a prochiral intermediat…
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