Access to Inherently and Centrally Chiral Calix[4]Arenes via Rhodium-Catalyzed C─H Activation and Insertion into Diverse Olefins and Alkynes.

Inherently chiral calix[4]arenes are important scaffolds in asymmetric catalysis and sensing, yet their enantioselective synthesis remains challenging due to limited synthetic methodology and lengthy synthetic routes. By resorting to rhodium-catalyze…

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