Construction of Tetrasubstituted α-Amino- and α-Alkoxy Phosphine Oxides via Pd-Catalyzed Regio- and Enantioselective Hydrophosphinylation of Dienes.

Significant progress has been made in the asymmetric hydrofunctionalization of dienes to construct vinylic stereogenic carbon centers. However, achieving enantioselective hydrofunctionalization of substituted dienes with heteroatom nucleophiles to fo…

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