Angewandte Chemie (International ed. in English)
Inverting Palladium-Phosphorus Lewis Pair Formation: Phosphonium Acting as Z-Type Ligand.
Lijun You, Nils Ansmann, Lutz Greb
Published: 202510.1002/anie.202519355
Abstract
Phosphorus-based ligands are prototypical L-type donors. Here, we introduce a Lewis acidic phosphonium cation that engages in unprecedented Z-type coordination to palladium(0). The resulting Pd→P(V) interactions are structurally unique and stronger t…
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