Advanced science (Weinheim, Baden-Wurttemberg, Germany)
Stereoselective Ferrier-Type O-Glycosylation Enabled by Difluoromethylated Glycal Donors.
You Zou, Hengfu Xu, Cang-Xin Zheng, Weiwei Zhang, Xin-Shan Ye, De-Cai Xiong
Published: 202510.1002/advs.202519766
Abstract
The effective construction of structurally homogeneous glycosides is requisite in oligosaccharide assembly and the development of carbohydrate-based drugs. A fluorine-mediated stereoselective Ferrier-type glycosylation is reported herein. Glycals are…
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